Well as a non-techy, non-engineer, non-mechanical type, just a regular everyday driver, can I offer my tuppence-worth!
Have had the PHEV since 8 September and until last week and about 840miles in had not used any petrol, then had a couple of shortish fast road journey and on each one using the save button, but then noticed all this chatter here and elsewhere about buttons/modes and fuel economy. So, yesterday I decided to try my own little experiment. As you can imagine, 6 weeks, 840 miles and all EV, this is by far the 'normal' set up for us and as we both work from home, commuting is never an issue and the car always gets the chance to get/remain topped up, but yesterday I went from Edinburgh to Elgin, round trip of 380 miles. So, outward trip first 5 miles on EV and then hit save with 19 miles range and did 60 miles on motorway, 95 miles on the A9, 30 miles on B-roads and 10 miles on A96; got to Elgin with EV range of 22miles, average mpg 34.8. Did a bit of EV driving around town and then headed home and did not touch any buttons at all this time. Took same route home and when I got onto the motorway (M90) after 120 miles driving, hit the charge button getting to the outskirts of Edinburgh with an EV range of 12 miles, which was enough to get to my son's to drop him off and then home, pulling into the drive with EV range of 1 and average mpg of 37.6!
Did I save fuel or money?? Don't really know, but when I used to do this exact same return journey in my previous 9+ year old SAAB estate it would be about 100 litres of petrol overall; tank was 60 litre capacity and it was just over a tank and a half. This time it took just over a tank, but the capacity is 40 litres, so I would say 50/55 litres! Now while a diesel vehicle would obviously give me masses more mpg, I do this 3-4 times a year, so it suits me!