Hi,
I'm not quite very experienced with my PHEV yet but I do have plug in experience in my previous car and I've also given it some thought for how this car works in order to get the best from it.
My conclusion is that you should use battery alone in urban driving (speeds below about 45mph) since ONLY series hybrid mode can be used if the engine is running and this is the LEAST efficient mode. Therefore, use battery to get to the motorway, use battery save mode on the motorway, and then switch back to battery once you leave the motorway.
IF you won't have sufficient battery to complete the urban part of the trip without running the engine in series hybrid mode then I think it is BETTER to use the charge mode while on the motorway to build JUST enough charge to complete the urban part on battery.
You should also aim to fully use the battery up on each trip by anticipating the drive ahead.
So to sum up, in my opinion only of course, use battery charge mode when the engine is running anyway, in order to avoid having a flat battery when travelling at speeds below about 45mph.
Another tip: Even on the motorway (when using battery mode is generally a poor choice since it depletes the battery very quickly and this is the most efficient time to run the engine in parrallel hybrid mode) when you are descending slight inclines and therefore using very little power switch back to battery mode in order to shut the engine off. Once the descent ends (which can often be a couple of miles or so on motorways) qyuickly select save mode again.
I hope you can understand the gist of what I'm trying to say even if my explanation isn't too clear.
Kind regards,
Mark